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81.
Swagata Chakraborty Susmitha A. L. Ramakrishna V. Hosur 《Magnetic resonance in chemistry : MRC》2012,50(9):587-591
Direct detection of 13C nucleus can be used as a valuable alternative where 1H detection poses a challenge due to relaxation effects, chemical exchange and poor chemical shift dispersion. In this context, we have designed a suite of 2D 13Cα‐detected hNCA experiments that provide sequential correlations of 13Cα with 15N on one hand and efficient spectroscopic labeling of certain groups of residues, namely, Gly, Ala, Ser and Thr, on the other. These residues act as checkpoints in the sequential walk, which in turn offer new possibilities of backbone assignment of small proteins from a set of 2D experiments, thereby providing great economy in terms of spectrometer time. The direct identification of peptide segments around Gly, Ala, Ser and Thr residues along a protein chain will be highly valuable for deriving important information on sites of ligand binding, phosphorylation, inhibitor/substrate binding, understanding protein folding pathways, comprehending local conformational dynamics etc. without having to obtain complete sequence‐specific assignments, which can be time consuming and at times formidable, especially in large proteins. We have illustratively demonstrated the multifaceted applications of these variants of 2D experiments on ubiquitin and M‐crystallin. We foresee that these 2D hNCA experiments will provide economic and efficient strategies for studying the structure and function of proteins. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
82.
Piotr Frąckiewicz 《Physics letters. A》2018,382(48):3463-3469
The Li–Du–Massar quantum duopoly model is one of the generally accepted quantum game schemes. It has applications in a wide range of duopoly problems. Our purpose is to study Stackelberg's duopoly with incomplete information in the quantum domain. The result of Lo and Kiang has shown that the correlation of players' quantities caused by the quantum entanglement enhances the first-mover advantage in the game. Our work demonstrates that there is no first-mover advantage if the players' actions are maximally correlated. Furthermore, we proved that the second mover gains a higher equilibrium payoff than the first one. 相似文献
83.
Shankari V. Rajagopal Kurt M. Fujiwara Ruwan Senaratne Kevin Singh Zachary A. Geiger David M. Weld 《Annalen der Physik》2017,529(8)
Ultracold atomic physics experiments offer a nearly ideal context for the investigation of quantum systems far from equilibrium. We describe three related emerging directions of research into extreme non‐equilibrium phenomena in atom traps: quantum emulation of ultrafast atom‐light interactions, coherent phasonic spectroscopy in tunable quasicrystals, and realization of Floquet matter in strongly‐driven lattice systems. We show that all three should enable quantum emulation in parameter regimes inaccessible in solid‐state experiments, facilitating a complementary approach to open problems in non‐equilibrium condensed matter. 相似文献
84.
《Communications in Nonlinear Science & Numerical Simulation》2014,19(6):1935-1944
This paper addresses the epidemiological modeling of computer viruses. By incorporating the effect of removable storage media, considering the possibility of connecting infected computers to the Internet, and removing the conservative restriction on the total number of computers connected to the Internet, a new epidemic model is proposed. Unlike most previous models, the proposed model has no virus-free equilibrium and has a unique endemic equilibrium. With the aid of the theory of asymptotically autonomous systems as well as the generalized Poincare–Bendixson theorem, the endemic equilibrium is shown to be globally asymptotically stable. By analyzing the influence of different system parameters on the steady number of infected computers, a collection of policies is recommended to prohibit the virus prevalence. 相似文献
85.
To safeguard analytical tractability and the concavity of objective functions, the vast majority of models belonging to oligopoly theory relies on the restrictive assumption of linear demand functions. Here we lay out the analytical solution of a differential Cournot game with hyperbolic inverse demand, where firms accumulate capacity over time à la Ramsey. The subgame perfect equilibrium is characterized via the Hamilton–Jacobi–Bellman equations solved in closed form both on infinite and on finite horizon setups. To illustrate the applicability of our model and its implications, we analyze the feasibility of horizontal mergers in both static and dynamic settings, and find appropriate conditions for their profitability under both circumstances. Static profitability of a merger implies dynamic profitability of the same merger. It appears that such a demand structure makes mergers more likely to occur than they would on the basis of the standard linear inverse demand. 相似文献
86.
《Physics and Chemistry of Liquids》2012,50(3):149-166
Abstract The structure factor for liquid lead at the temperatures 613 K, 643 K, 863 K and 1163 K are measured by neutron diffraction. Extensive comparisons to earlier measurements are made as well as comparisons to different hard-core models. 相似文献
87.
《Physics and Chemistry of Liquids》2012,50(4):345-349
Abstract Isobaric vapour-liquid equilibrium data are measured at 200, 500 and 707 mm Hg at ten compositions spread evenly over the entire liquid mole fraction range, employing a Swietoslawski type ebulliometer. The liquid phase composition vs. bubble temperature (x-t) data are found to be well represented by Wilson model The optimum Wilson parameters are used to calculate the vapour phase compositions, activity coefficients and the excess Gibbs free energies. 相似文献
88.
A water-soluble derivative of chitosan, carboxymethylchitosan (CMCH), was mixed with alkyltrimethylammoniumbromides (CmTAB) and was studied on the adsorption at air/water interface using equilibrium and dynamic surface tension method. The effects of surfactant and polymer concentrations, surfactant chain length, as well as pH of solution were investigated. Addition of the surfactants remarkably promotes the polymer adsorption. Increasing any one of surfactant concentration, surfactant chain length, and pH will facilitate the adsorption of the mixture whereas little effects of polymer concentration were observed. The results are explained in terms of the interaction between CMCH and CmTAB under different conditions. 相似文献
89.
90.